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The Nature of the Active Catalyst in Late Transition Metal-Mediated Ring-Opening Polymerization (ROP) Reactions: Mechanistic Studies of the Platinum-Catalyzed ROP of Silicon-Bridged [1]Ferrocenophanes

✍ Scribed by Temple, Karen; Jäkle, Frieder; Sheridan, J. B.; Manners, Ian


Book ID
126836326
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
135 KB
Volume
123
Category
Article
ISSN
0002-7863

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Transition Metal-Catalyzed Ring-Opening
✍ Alexandra Bartole-Scott; Rui Resendes; Ian Manners 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 162 KB

## Abstract The transition metal‐catalyzed ring‐opening polymerization of dimethyl[1]silaferrocenophane (fcSiMe~2~) (1), fc = Fe(__η__‐C~5~H~4~)~2~), in the presence of MePhSiH~2~, or the chlorosilanes ClMe~2~SiH, ClMePhSiH, or ClPh~2~SiH has been shown to allow access to poly(ferrocenylsilane)s R^