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The Nature of One-sided Intergrowths on (001) of Triclinic Centrosymmetric K2Cr2O7

โœ Scribed by Dipl. Krist. G. Heide; Prof. Dr. H. Follner


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
770 KB
Volume
31
Category
Article
ISSN
0232-1300

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โœฆ Synopsis


Institsilt fiir Mineralogie und Mineralische Rohstoffe der Technixhen IJniversitiit Clausthel, Germany

The Nature of One-sided Intergrowths on (00%) of Triclinic Centrosymmetric KzCrz07 1) Systematic composite crystal growth can arise when larger crystals of the same type exhibit oriented intergrowth. One example of this is potassium dichromate (Pi) which SHUBNIKOV first described in 1912. In highly supersaturated solutions, a one-sided roughening of its crystals occurs on (OOT). Electron micrographs show that this is due to the growth of platelet-shaped crystals. Optical and X-ray methods as well iu electron channeling and BACK-KIKUCHI diffraction patterns have shown that the growths are predominantly parallel intergrowths, about 10% of which are twins according to [OlO].

Systematischc Kristallverwachsungen konnen dadurch entstehen, daR groRere gleichartige Kristalle orientiert miteinander verwarhsen. Ein Beispiel dafiir ist das 1912 diirch SHUBNIKOV bekannt gewordene Kaliumdichromat (Pi), dessen Kristalle in hoher iibersattigten Losungen einseitig auf (OOi) aufrauhen. Elektronenmikroskopische Aufnahmen zeigen, dal3 es sich dabei um Aufwachsungen von plattenformigen Kristallen handelt. Mit optischen und rontgenographischen Methoden und niit Hilfe von Elektronen-CHANNELLING bzw. mit Reflexions-Klliuc:HI-Beugungsa.ufnahrnen wird g?zeigt, daf3 es sich hei den Aufwachsungen iiberwiegend urn Parallelverwachsungen und zu etwa 10% um Vcrzwillingungen nach [OlO] handelt.

') 27th Comrnunicn.tion.


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