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The nature of autocatalysis in the Butlerov reaction

✍ Scribed by A. N. Simonov; O. P. Pestunova; L. G. Matvienko; V. N. Parmon


Book ID
110170837
Publisher
Springer
Year
2007
Tongue
English
Weight
218 KB
Volume
48
Category
Article
ISSN
0023-1584

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It is shown that the reaction between NO and CO on Pt(100) is autocatalytic and probably involves a surface species which accelerates the reaction. Temperature-programmed desorption (TPD) of co-adsorbed NO and CO yields complete reaction, with N2 and CO2 desorbing simultaneously in sharp peaks at =4