✦ LIBER ✦

The Nanocrystalline Nickel with Catalytic Properties on Methanol Oxidation in Alkaline Medium

✍ Scribed by R. M. A. Tehrani; S. Ab Ghani

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 454 KB
Volume: 9
Category: Article
ISSN: 1615-6846
DOI: 10.1002/fuce.200800122

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The hexagonal closed packed (hcp) nanocrystalline nickel (Ni), with an average diameter of 9.7 ± 2.27 nm was deposited uniformly on composite graphite (CG) by the rapid scanning (6,500 mVs^–1^) voltammetry technique. The hcp‐nano Ni‐modified CG electrode was investigated for the catalytic oxidation of methanol in alkaline medium through the formation of NiOOH. A high anodic current was obtained at peak potential of +570 mV vs Ag/AgCl. Both the scan rate and the methanol concentration affected the oxidation of methanol. The results showed that catalytic activity had increased with decrease in Ni particle diameter. It was also shown that the hcp‐nano Ni/CG modified electrode was the most efficient catalyst in the oxidation of methanol.

📜 SIMILAR VOLUMES

The Nanocrystalline Nickel with Catalyti

The Nanocrystalline Nickel with Catalytic Properties on Methanol Oxidation in Alkaline Medium

✍ R. M. A. Tehrani; S. Ab Ghani 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 34 KB

Electrocatalytic Oxidation of Methanol o

Electrocatalytic Oxidation of Methanol on a Nickel-Porphyrin IX Complex Modified Glassy Carbon Electrode in Alkaline Medium

✍ S. M. Golabi; A. Nozad 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 687 KB

Study on Effect and Catalytic Mechanism

Study on Effect and Catalytic Mechanism of the Catalysts for Coal Oxidation in Alkaline Medium

✍ Huaiyou Liu; Jingkang Lü; Yonggang Zhao; Wei Zhou; Renhe Yin 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 589 KB

The hydrogen evolution reaction in alkal

The hydrogen evolution reaction in alkaline medium on nickel modified with W042− or Mo042−

✍ O. Savadogo 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 184 KB

Nickel was modtfied at the surface from alkalme solution contamrng dtfferent concentrattons of WO,% or MoG4= It was shown that improvement in the overpotential (n) and in the exchange current density of the hydrogen evolution reaction m KOH 3M on the electrode depends on the nature of the heteropoly

Ni/SiO2 catalysts prepared with ethylene

Ni/SiO2 catalysts prepared with ethylenediamine nickel precursors: Influence of the pretreatment on the catalytic properties in glucose hydrogenation

✍ Sabine Schimpf; Catherine Louis; Peter Claus 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 914 KB

Effect of solvent on the reactions of co

Effect of solvent on the reactions of coordination complexes: Part 16. Kinetics and mechanism of complexation of oxalatopentaammine-cobalt(III) with nickel(II) in methanol-water medium

✍ Anadi C. Dash; Jyotshamayee Pradhan 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 468 KB 👁 1 views

## Abstract The kinetics of reversible complexation of oxalatopentaammine cobalt(III) with Ni^2+^ has been investigated in MeOH + water media (0–50 (v/v) % MeOH) at 15.0–35.0°C and I = 0.10 mol dm^−3^. Analysis of rate data indicates that the monobonded complex [(NH~3~)~5~ · CoOCOCO~2~Ni]^3+^ in wh