The ionization behavior of carboxylic acids including aliphatic chain fatty acids and bile acids in solutions, micelles, membranes and proteins is of considerable biological interest. The 13C nuclear magnetic resonance chemical shift of carboxyl carbon of a variety of acids has been shown to be a li
โฆ LIBER โฆ
The motion of aromatic molecules in bile acid micelles
โ Scribed by B.M. Fung; Leon Thomas Jr.
- Book ID
- 103042082
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 358 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0009-3084
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โฆ Synopsis
Deuterium spin-lattice relaxation time (T~) ofperdeuterobenzene and perdeuteronaphthalene dissolved in aqueous solutions of sodium deoxycholate and sodium cholate was studied. By comparing the experimental data and theoretical calculations, it was concluded that benzene and naphthalene are not held stationary in the bile acid miceUes, and their molecular planes have certain librational motion. In addition, benzene undergoes rapid rotation about the C 6 axis, but naphthalene does not rotate in its molecular plane.
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