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The Most Twisted Amide: Structure and Reactions

✍ Scribed by Anthony J. Kirby; Igor V. Komarov; Peter D. Wothers; Neil Feeder

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 81 KB
Volume: 37
Category: Article
ISSN: 0044-8249
DOI: 10.1002/(sici)1521-3773(19980403)37:6<785::aid-anie785>3.0.co;2-j

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✦ Synopsis

The title amide 1 behaves more like a ketone-up to a point! The crystal structure of this (90°) twisted amide shows a pyramidal nitrogen atom next to a planar carbonyl group.

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