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The Morita–Baylis–Hillman reaction in aqueous–organic solvent system

✍ Scribed by Rodrigo O.M.A. de Souza; Vera L.P. Pereira; Pierre M. Esteves; Mario L.A. A. Vasconcellos


Book ID
104095678
Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
176 KB
Volume
49
Category
Article
ISSN
0040-4039

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✦ Synopsis


We have found that water and organic solvents mixed at different proportions can give good to excellent yields and short reaction times for the Morita-Baylis-Hillman reaction. The present Letter details our findings in the Morita-Baylis-Hillman reaction between several aromatic aldehydes and methyl acrylate or acrylonitrile. The selection of the catalyst was also evaluated and DABCO affored the best results when compared to DBU, DMAP, HMT, Imidazole and Triethylamine.


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ChemInform Abstract: The Morita—Baylis—H
✍ Rodrigo O. M. A. de Souza; Vera L. P. Pereira; Pierre M. Esteves; Mario L. A. A. 📂 Article 📅 2009 🏛 John Wiley and Sons ⚖ 36 KB 👁 2 views

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