The monodentate 4,4′-bipyridine complex tetraaquabis(4,4′-bipyridine)zinc(II) bis(4-carboxybenzenesulfonate)
✍ Scribed by Zhang, Li-Ping ;Zhu, Long-Guan
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 194 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The monodentate 4,4 0 0 0 -bipyridine complex tetraaquabis(4,4 0 0 0 -bipyridine)zinc(II) bis(4-carboxybenzenesulfonate)
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The crystal structure of the title complex, [Co(C 9 H 7 O 5 ) 2 -(C 10 H 8 N 2 ) 2 (H 2 O) 2 ]Á4H 2 O or [Co(4-CPOAH) 2 (4,4 0 -bipy) 2 -(H 2 O) 2 ]Á4H 2 O (4,4 0 -bipy is 4,4 0 -bipyridine and4-CPOAH À is the 4-carboxyphenoxyacetate monoanion), consists of two independent mononuclear molecules that
The centrosymmetric structure of {Zn[S 2 CN(CH 2 Ph) 2 ] 2 } 2 (4,4 -bipy) features chelating dithiocarbamate ligands so that a trigonal bipyramidal NS 4 coordination geometry for zinc results.