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The monoclinic phase of true NASICON: Structure, correlations and transition

โœ Scribed by G. Collin; R. Comes; J.-P. Boilot; P. Colomban

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
151 KB
Volume
28-30
Category
Article
ISSN
0167-2738

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โœฆ Synopsis

~[ated to the monodinie mo~ifi~ti~ of a-NasSe,(POa }~; fe~leetri~ym order with four kihdS of o~picd Na sit~: Na( I 1, ~ular Na( 2)', d~plac~ ga{ 3)' and mid~a. Di~defing ~lti~ ~m both P~i s~bstitulion and from nun~ichiomcl ~ s~ening~fth~ng-~n~e~ ~ads1~a ~d~o~u~n~yo~ t~e r~gu~er Na(~ ~ si~e' Type~L p~tfor x~ 2.2~ ~nds io an anfi.f~el~t rie I~a~ ord~ wish thee zy~s of o~vied Na sil~ Na(I ), regular Nal3}' ond micbNa TiC Naf2 F nile is ~y. Thc~ i$ ag~u ofi~ a ~sidu~ ~r ~thr NR( $ ) ~te. T~ gxislencr of~ int c~ili~l mld.NR si~e est,bli~es ~hat Ihe ~on-ion ~lafion~ provldc an ess~thi pm ~ I~ site ~tentia~ a~ thin tie dnvi~ mechanism for the ph ~r tmnshion is pr~neipallyd~wlhemod~fi~l~onoflhe~:~l-lani~polafi~l~onby*ht~ndueting~o.s,

๐Ÿ“œ SIMILAR VOLUMES

Nasicon analog Na3Sc2(PO4)3: Thermal beh
Nasicon analog Na3Sc2(PO4)3: Thermal behaviour of the ฮฑ, ฮฒ and ฮณ types, structure, correlations and transitions
โœ G. Collin; R. Comes; J.-P. Boilot; Ph. Colomban ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 145 KB

The ~tal m~u~ of the thee c~t~] t~ of~hr SC NAStCON an~l~ a~ in~e~i~t~ b=l~ r~ ~0 s~d 60O ~ A ~s~tlc ~p~ey of Ihr mld-Na silr is ~nd ex~pl in the I~lem~t u~ p~sr ort~ 0 t~ '~qlh ~n~a~ing tem~tu~ ,~ is ~ tra~f~ U~ Na( I ) into mi~.Na sites, whereas t~ N~( 2 ) si~ ~tai~s a ~n~t~t o~u~aacy of 2 ~ u~it