The monoclinic framework structure of zeolite H-ZSM-5. Comparison with the orthorhombic framework of as-synthesized ZSM-5
β Scribed by H. van Koningsveld; J.C. Jansen; H. van Bekkum
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 618 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0144-2449
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The transition temperature (340 K) and enthalpy change (3.7 + 0.5 kJ mo1-1) of the monoclinic-orthorhombic phase transition in highly siliceous zeolite ZSM-5 (Si/AI = 639) were measured by differential scanning calorimetry (d.s.c.). The transition temperature determined is in agreement with that due
The structures and energetics associated with the adsorption of ethene and four butene isomers on H-ZSM-5 zeolite have been studied using a 46T cluster and calculated at the ONIOM2(B3LYP/6-311++G(d,p):UFF) level. The adsorption energy for ethene-zeolite complex is predicted to be -8.17 kcal/mol, whi