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The molecular structures of bis(pentamethylcyclopentadienyl)-calcium and -ytterbium in the gas phase; two bent metallocenes

✍ Scribed by Richard A. Andersen; James M. Boncella; Carol J. Burns; Richard Blom; Arne Haaland; Hans V. Volden


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
245 KB
Volume
312
Category
Article
ISSN
0022-328X

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The gas-phase molecular structures of bis(dichlorosily1)amine, (HSiCl,),NH, and bis(dichlorosilyl)methylamine, (SiHCl,),NMe, have been investigated by electron diffraction and ab initio calculations on a MP2/6-31G\* level. Because the latter suggest the presence of a mixture of two conformers for ea