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The molecular structure of PrI3and GdI3as determined by synchronous gas-phase electron diffraction and mass spectrometric experiment assisted by quantum chemical calculations

✍ Scribed by Nina I. Giricheva; Sergey A. Shlykov; Elena A. Lapykina; Heinz Oberhammer; Georgiy V. Girichev


Publisher
Springer
Year
2011
Tongue
English
Weight
410 KB
Volume
22
Category
Article
ISSN
1040-0400

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The molecular structure and conformation of tris(cyclopropylsilyl)amine (TCPSA) has been studied by means of gas-phase electron diffraction at 338 K and quantum-chemical calculations. A total of 12 relatively stable conformations of TCPSA molecule were considered. According to the experimental resul