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The molecular structure of 7-syn-6-endo-dihydroxybicyclo [2.2.1]heptane 2-endo-carboxylic acid-α-lactone

✍ Scribed by R.M. Moriarty; Harsh Gopal; J.L. Flippen; J. Karle


Book ID
108383298
Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
163 KB
Volume
13
Category
Article
ISSN
0040-4039

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Structure of the iodo-lactone derived fr
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In a recent comunication, Risinqer, Green and Green' have suggested that the iodo-lactone obtained2 frcm the action of iodine and potassium iodide in alkaline solutior. on norborn-S-ene-2-endo-carboxylic acid should be formulated aa 6-exo-iodo-S-endo-hydroxynorbornane-2-endo-carboxylic acid leotone

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endo-Bicyclo[2.2.2] oct-5-ene-2-carboxylic acid, in acidic solution, cyclizes to give a mixture of three isomeric lactones. These three isomers have different stabilities and are partly interconvertible, but their simultaneous decomposition makes the experimental study of these equilibria difficult