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The molecular structure and conformational behaviour of 3-methyl-3-phenyl-cyclopropene

✍ Scribed by M. Traetteberg; A. De Meijere; I.N. Domnin

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
587 KB
Volume
128
Category
Article
ISSN
0022-2860

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X-Ray diffractometry of methyl 3,4-anhydro-a-nL-allopyranoside (3) revealed the crystals to be monoclinic, space group Cc, with cell dimensions a = 6242(l), b = 16.987(2), c = 7.739(l) A; /I = 106.09(l)", Z = 4. The 3,4\_anhydropyranose ring adopts a hybrid 'E + '&conformation. Relatively strong int