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The mobility of polymer melts

✍ Scribed by Servaas Vleeshouwers; Erik Nies


Book ID
104164053
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
325 KB
Volume
35
Category
Article
ISSN
0032-3861

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✦ Synopsis


An empirical equation is presented to describe the mobility of polymer melts as a function of temperature and pressure. This is accomplished in terms of the order parameter in a hole theory and temperature, combined in a Fulcher-Tammann-Hesse type equation. Experimental data for various amorphous polymers are described successfully.


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## Abstract Detailed knowledge on chain mobility in polymers is of fundamental interest in order to understand their mechanical properties. As a specific example, the melting behavior of semicrystalline polyethylene can be studied by thermal analysis and NMR spectroscopy. In ultra high molecular we