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The Mixed Complexes of Ni(II) in Aqueous Solutions Containing Ethylenediamine and β-Alanine

✍ Scribed by L. C. van Poucke; M. A. Herman


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
312 KB
Volume
77
Category
Article
ISSN
0037-9646

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In aqueous solution, bis(nucleoside) complexes formed by the reaction of cis-[Pt(NH3)2(H2O)2]2+ with an excess of either adenosine (ado) or a mixture of adenosine and guanosine (guo) undergo a slow N7--> N1 linkage isomerisation in the adenine moiety. The isomerisation probably involves the breaking