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The Millimeter-Wave Spectra of 1-Chloro-1-fluoroethylene and cis-1-Chloro-2-fluoroethylene

โœ Scribed by J.L. Alonso; A.G. Lesarri; L.A. Leal; J.C. Lopez

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
542 KB
Volume
162
Category
Article
ISSN
0022-2852

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โœฆ Synopsis

The ground vibrational state microwave spectra of the ({ }^{35} \mathrm{Cl}) and ({ }^{37} \mathrm{Cl}) isotopomers of 1-chloro1-fluoroethylene and cis-1-chloro-2-fluoroethylene have been sludied in the frequency range 26(245 \mathrm{GH}). Chlorine nuclear quadrupole coupling constants have been obtained from first-order analyses of the frequencies of 100 hyperline components for cach isotopomer. Rotational constants and quartic and sextic centrifugal distortion constants have been determined from fits to large numbers of central transition frequencies. A brief description of the computer-controlled source modulation millimeter-wave spectrometer used in this work is given. (\quad 1943). Academic Press. Inc

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## Abstract The kinetics and mechanisms of the dehydrochlorination of 2โ€chloroโ€1โ€ phenylethane, 3โ€chloroโ€1โ€phenylpropane, 4โ€chloroโ€1โ€phenylbutane, 5โ€chloroโ€1โ€phenylpentane, and their corresponding chloroalkanes were examined by means of electronic structure calculation using density functional theo