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The microwave spectrum of the open-shell complex ArNO2

✍ Scribed by Russell J. Low; Christopher J. Whitham; Thomas D. Varberg; Brian J. Howard

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 559 KB
Volume: 222
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)00369-6

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✦ Synopsis

The 505t404, 404+303, 303+202 and 2,-,2 c lo, rotational transitions of the open-shell van der Waals complex ArN02 have been observed using a Fourier-transform microwave spectrometer. The complex was produced by supersonic expansion of NO1 gas in argon. The spectrum showed fine, magnetic hypertine and electric quadrupole structure. The data have been fitted to a semirigid Hamiltonian to determine the molecular parameters for the K,=O state. We discuss the implications of these derived parameters for the electronic and geometric structure of the complex.

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