✦ LIBER ✦

The microwave spectrum of argon-phosphorus trifluoride

✍ Scribed by Kurt W. Hillig II; Jose Matos; Anthony Scioly; Robert L. Kuczkowski

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 291 KB
Volume: 133
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)87082-3

No coin nor oath required. For personal study only.

✦ Synopsis

The argon-PF3 complex has been prepared in a supersonic expansion of Ar (98%) and PFr (2%). A Fourier-transform microwave spectrometer employing a Fabry-Perot cavity was used to assign 28 rotational transitions. The rotational constants (MHz) and distortion constants (kHz) were A=7332.468( 10), B= 1023.055(2), C=952.564(2), 0,=3.53(l), D,,=60.4(1) and d, = -0.240(7). The argon atom is 3.953 A (rem ) from the PF, center ofmass and r,, makes an angle of 70.3" with the C, axis of the PF3.

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