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The Methoxymercuration of 1,3-Butadiene

✍ Scribed by McNeely, K. H.; Wright, George F


Book ID
127264726
Publisher
American Chemical Society
Year
1955
Tongue
English
Weight
300 KB
Volume
77
Category
Article
ISSN
0002-7863

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Reaction of l, l-dimethoxy-2-butyne (II) with sodium methoxlde m dlmethyl sulfoxlde at 100" yields (L?.)-1, 3-dlmethoxybutadlene (III) (20-3%) The dlene III undergoes ready Duels-Alder reaction with malelc anhydride, N-phenyltrlazolmedlone and dimethyl acetylenedlcarboxylate