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The Metal-Carbon Bond: Vol. 1 (1983) || Syntheses of transition metal-carbyne complexes

✍ Scribed by Hartley, Frank R.; Patai, Saul


Book ID
120082663
Publisher
John Wiley & Sons, Ltd.
Year
1983
Weight
760 KB
Category
Article
ISBN
0471100587

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Carbonylation of Transition-Metal Carbyn
✍ Dr. Fritz R. Reissl; Dipl.-Chem. Wolfgang Uedelhoven; Dipl.-Chem. Karl Eberl πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 141 KB πŸ‘ 2 views

**Surprising reactions of carbon monoxide with transition metal complexes** have been observed with compounds __(1)__ and __(2)__. The carbyne complex __(1)__ takes up CO at normal pressure and βˆ’30Β°C to form the metalated ketene __(2)__ which itself is deoxygenated by CO at +60Β°C and under 60atm pre