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The metal-ammonia reduction of ketones

โœ Scribed by Huffman, John W.; Charles, J. T.


Book ID
121418660
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
981 KB
Volume
90
Category
Article
ISSN
0002-7863

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The hypothesis of Pradhan that alkali metal/NH3 reductions of saturated ketones lead to ketone &anions which then deprotonate unreacted ketone can be excluded because the dianions would have been protonated in experiments in which 50-110 equiv of tert.-Bush, Et&L, and H20 were present in the reactio