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The mechanisms of the oxidation of NADH analogues 1. Photochemical oxidation of N-unsubstituted 1,4-dihydropyridines by various acceptors

✍ Scribed by M.B. Taraban; A.I. Kruppa; N.E. Polyakov; T.V. Leshina; V. Lūsis; D. Muceniece; G. Duburs


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
652 KB
Volume
73
Category
Article
ISSN
1010-6030

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The reaction kinetics of the reactions of Hantzsch esters (HEH) and Hantzsch 4-aryl-1,4-dihydropyridines (4aryl-HEH) with the tropylium cation as a formal hydride acceptor were investigated. The observed kinetic isotope effect (KIE, k H /k D ), using HEH and 4,4-d 2 -HEH as substrates, was 4.16, sug