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The Mechanism of the Wurtz—Fittig Reaction. The Direct Preparation of an Organosodium (Potassium) Compound from an RX Compound

✍ Scribed by Gilman, Henry; Wright, George F.

Book ID
127273162
Publisher
American Chemical Society
Year
1933
Tongue
English
Weight
271 KB
Volume
55
Category
Article
ISSN
0002-7863

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The revised structure of an oxidation pr
The revised structure of an oxidation product from the reaction of an α-tocopherol model compound, 2,2,5,7,8-pentamethylchroman-6-ol, with potassium superoxide; 6 -hydroxy -2,2,6,7,8- pentamethylchroman- 5 (6H) -one1
✍ Shigenobu Matsumoto; Mitsuyoshi Matsuo; Yoichi Iitaka 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 211 KB

The previously reported structure of an oxidation product obtained from the reaction of an a-tocopherol model compound(l) with KO, is revised to 6-hydroxy-2,2,6,7,8-pentamethylchroman-S(6H)-one(3) on the basis of the X-ray crystallographic and '\*O-labeling studies. An oxidation product has been ob