The mechanism of the tschitschibabin reaction
β Scribed by R.A. Abramovitch; F. Helmer; J.G. Saha
- Book ID
- 104240675
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- French
- Weight
- 118 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
The aminstion of pyriiire and its derivatives has ger:erilly been discussed ir terms of an a.tdition-elivdxstion mechanism via a c-corplcx in--termediate, but more recently the possibility +hat it may proctcj. by L mechanism involving ti 2,3-gyrilyne intermediate has bean sug--esteJ. (1,.
π SIMILAR VOLUMES
Table 1. Side-chain alkylation of toluene with ethylene. Cr-Ni-Mo steel autoclave (314 cm'), 20 g (217 mmol) toluene, 7 g (250 mmol) ethylene. 380 C. 55 atm, 2 h. C , H,CH,Br Toluene Yield [mol-";,I all straight [ w1:y J conversion n-propyi-,~-pentyl-chain alkyl-C%1 benzene benzene benzenes