𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The mechanism of the tschitschibabin reaction

✍ Scribed by R.A. Abramovitch; F. Helmer; J.G. Saha


Book ID
104240675
Publisher
Elsevier Science
Year
1964
Tongue
French
Weight
118 KB
Volume
5
Category
Article
ISSN
0040-4039

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✦ Synopsis


The aminstion of pyriiire and its derivatives has ger:erilly been discussed ir terms of an a.tdition-elivdxstion mechanism via a c-corplcx in--termediate, but more recently the possibility +hat it may proctcj. by L mechanism involving ti 2,3-gyrilyne intermediate has bean sug--esteJ. (1,.


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Table 1. Side-chain alkylation of toluene with ethylene. Cr-Ni-Mo steel autoclave (314 cm'), 20 g (217 mmol) toluene, 7 g (250 mmol) ethylene. 380 C. 55 atm, 2 h. C , H,CH,Br Toluene Yield [mol-";,I all straight [ w1:y J conversion n-propyi-,~-pentyl-chain alkyl-C%1 benzene benzene benzenes