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The Mechanism of the Titanium-Catalyzed Hydroaminoalkylation of Alkenes

✍ Scribed by Insa Prochnow; Patrick Zark; Prof. Dr. Thomas Müller; Prof. Dr. Sven Doye

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
419 KB
Volume
50
Category
Article
ISSN
0044-8249

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A high catalytic activity towards alkene epoxidation is shown by titanium‐modified MCM41 mesoporous silicas if 2‐methyl‐1‐phenyl‐2‐propyl hydroperoxide (MPPH) is used as oxidant. This first example in which MPPH has been used as an efficient two‐electron oxidizing agent demonstrates that it is a com