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The mechanism of the tertiary amine catalysed isomerisation of endoperoxides to hydroxyketones: synthesis and chemistry of the intermediate postulated in the peroxide attack mechanism

✍ Scribed by David R. Kelly; Harjinder Bansal; J.J.Gwynfor Morgan

No coin nor oath required. For personal study only.

✦ Synopsis

Evidence is presented which demonstrates that the Kornblum-DeLaMare rearrangement does not proceed via nucleophilic attack of the peroxide linkage.

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