The Mechanism of the Slow Oxidation of Propane
β Scribed by Pease, Robert N.
- Book ID
- 127146262
- Publisher
- American Chemical Society
- Year
- 1935
- Tongue
- English
- Weight
- 394 KB
- Volume
- 57
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Mathematical modeling was used for the kinetics of gas-phase propane oxidation at 586,613, and 658 K and pressures 172 and 250 torr. The reaction mechanism involving branching by decay of the peracetyl peroxy radical, and oxygen-containing products formed on decay of the RO, radical is discussed. Fa
4 low-temperature matrix isolation method has been developed which makes possible the isolation and detection of HO2 radicals from a gas-phase radical chain-reaction system conta-ining atomic H, 0 and O H radicals as well. The formation of HOt radicals is demonstrated in the rarified hydrogen flame.
Analyses of the products of the slow combustion of propane in oxygen by flow and static methods have been made. Peroxides are found only when the surface does not destroy them too fast to prevent their detection. In the vapor state hydrogen peroxide appears to be mainly present and dihydroxymethyl