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The mechanism of “the second kind of maximaå at the rotated dropping mercury electrode as studied by using the magnetic field effect

✍ Scribed by Shizuo Fujiwara; Yoshio Umezawa


Publisher
Elsevier Science
Year
1972
Weight
161 KB
Volume
34
Category
Article
ISSN
0022-0728

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✦ Synopsis


To summarize the experimental observations: it was found possible in the given case to verify the validity of eqn. (1). For a specific example we were successful in verifying the applicability of our method to the study of adsorption phenomena occurring during electrode reactions.


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An external magnetic field is found to retard the photoisomerization of tram-3,3-dimethyl-1-( 2-naphthyl)-1-butene (t-DMNB) in degassed acetonitrile in the presence of electron acceptors. From this and other observations, the precursor of the isomerization is indicated to be the oletin triplet arisi