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The Mechanism of the Pyrolysis of 2, 2, 3, 3-Tetramethylbutane

โœ Scribed by Marshall, R. M.; Purnell, J. H.; Storey, P. D.

Book ID
120151346
Publisher
The Royal Society
Year
1978
Tongue
English
Weight
735 KB
Volume
363
Category
Article
ISSN
0962-8444

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Gas-phase pyrolysis of 2,2,3,3-tetrameth
Gas-phase pyrolysis of 2,2,3,3-tetramethylbutane using a wall-less reactor
โœ Jay E. Taylor; Thomas S. Milazzo ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 529 KB

## Abstract The pyrolysis of 2,2,3,3โ€tetramethylbutane (TMB) has been studied using the wallโ€less reactor. Under homogeneous conditions up to 670ยฐC, the activation energy is 43.2 kcal/mol and log __A__ is 10.70. The products are 2โ€methylpropene, hydrogen, propene, 2โ€methylโ€2โ€butene, ethane, ethene,

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Very low-pressure pyrolysis (VLPP) of alkanes: n-butane, 2,3-dimethylbutane, 2,2โ€ฒ,3,3โ€ฒ -tetramethylbutane, and isobutane
โœ D. M. Golden; Z. B. Alfassi; P. C. Beadle ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 537 KB

The four species in the title were decomposed under VLPP conditions at temperatures in the vicinity of 1100ยฐK. Three model transition states were constructed that fit the low-pressure data thus obtained and that also yield If EZSS = AEZSS; 2) &OO = A&oo; 3 ) log Alloo = 16.4 per C-C bond broken. Th