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The mechanism of the photo-induced decarboxylatton of pyruvic acid in solution

โœ Scribed by R.Stephen Davidson; Dean Goodwin; Ph.Fornier De Violet

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
359 KB
Volume
78
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

It is proposed that photo-induced decarbo\ylatlon of pyruvic acid occurs via electron transfer from an excited to a ground-state molecule. Quantum yields of triplet production at 295 I( in deoxygenated benzene, acetonitrile and water are 0.65,0.88 and 0.22. The triplet state of naphthalene is quenched by pyrutic acid and It 1s suggested t!mt this occurs via electron transfer.

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