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THE MECHANISM OF THE OXIDATION OF GLUCOSE BY BROMINE IN NEUTRAL AND ACID SOLUTIONS.

โœ Scribed by Bunzel, H. H.; Mathews, A. P.

Book ID
127287833
Publisher
American Chemical Society
Year
1909
Tongue
English
Weight
799 KB
Volume
31
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

The kinetics and mechanism of the oxidat
The kinetics and mechanism of the oxidation of formic acid by bromine in acid aqueous media
โœ M. A. Brusa; A. J. Colussi ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 326 KB ๐Ÿ‘ 1 views

The reaction between formic acid and bromine in strongly acid aqueous media at 298 K Brz + HCOOH -2 Br-+ 2 H+ + COz was studied by absorption spectrophotometry (A = 447 nm). Reaction rates, expressed as H = -d[Brz]/dt, depend on the concentrations of HCOOH (0.3-2.4M), Br2[(2.7-13.6) X 10-3M], H+ (0.

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The kinetics and mechanism of the reaction between nitrous acid and bromine are studied in dilute sulfuric acid medium, using both the stopped-flow method and conventional spectrophotometry. The partial reaction order with respect to Br 2 moderately differs from 1, showing a saturation at a higher c