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The mechanism of the olefin-to-carbene rearrangement for 9-phenyl-1(9)-homocubene

✍ Scribed by Eaton, Philip E.; White, Andrew J.

Book ID
126516547
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
993 KB
Volume
55
Category
Article
ISSN
0022-3263

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The mechanism of the photooxidation of 1
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## Abstract Irradiation of 1‐(9‐phenanthryl)‐4‐phenylbutenyne (**1**) in aprotic solvents containing oxygen gives two products, namely a photocyclization product, 1‐phenyltriphenylene **3**, as is usually formed from diarylbutenynes, and a photooxidation product (2), derived from cyclopropapyrone.