With a view to clarifying analogies and differences between the mechanisms involved in the nitrosation of amino acids and secondary amines, we studied the kinetics of the nitrosation of five imino acids (azetidine-2carboxylic acid, pyrrolidine-2-carboxylic acid, piperidine-2-carboxylic acid, piperid
The mechanism of the nitrosation of ?-amino acids: evidence for an intramolecular pathway
✍ Scribed by Casado, Julio; Castro, Albino; Leis, J. Ram�n; Mosquera, Manuel; Pe�a, M. Elena
- Book ID
- 125854673
- Publisher
- Royal Society of Chemistry
- Year
- 1985
- Tongue
- English
- Weight
- 592 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1472-779X
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The relative importance of three different routes for the N-nitrosation of amino acids (nitrosation by N 2 O 3 , by and by intramolecular migration of the nitroso group from the initially nitrosated carboxylate group) was investigated for methylaminobutyric acid, methylaminoisobutyric acid, azetidin
The kinetics of the nitrosation of methyl, ethyl. propyl. butyl, and ally1 urea were studied by conventional and stopped-flow spectrophotometry in the presence or absence of acetate or mono-di-, or trichloroacetate anions In the presence of a large excess of urea, the observed rate equation was whe