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The mechanism of the bromination of hexamethylbenzene in acetic acid

✍ Scribed by Enrico Baciocchi; Maria Casula; Gabriello Illuminati; Luigi Mandolini

Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
199 KB
Volume
10
Category
Article
ISSN
0040-4039

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✦ Synopsis

According to the two-stage mechanism of electrophilic aromatic substitution, the halogenation by molecular chlorine and bromine can be formulated by equations ( 1) and ( 2), respectively*.

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## Abstract Hydrogen bromide is known to inhibit the bromination of aromatic substrates (ArH), either by fixing up bromine as HBr~3~ or ArH as ArH Β· HBr. However, there is catalysis by HBr in the bromination of mesitylene in acetic acid. The bromination of __o__‐xylene in acetic acid in the dark is

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