The mechanism of copper(I)-catalyzed olefin cyclopropanation with diazomethanes has been studied at the BP86/AE1 level of density-functional theory. For the model system Cu(diazabutadiene) + + ethene + diazomethane, copper carbene complexes are confirmed as viable intermediates, with rate-determinin
The Mechanism of the (Bispidine)copper(II)-Catalyzed Aziridination of Styrene: A Combined Experimental and Theoretical Study
โ Scribed by Peter Comba; Carolin Lang; Carlos Lopez de Laorden; Amsaveni Muruganantham; Gopalan Rajaraman; Hubert Wadepohl; Marta Zajaczkowski
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 623 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0947-6539
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