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The Mechanism of the Alkaline Hydrolysis of p-Nitrophenyl N-Methylcarbamate 1

โœ Scribed by Bender, Myron L.; Homer, R. B.

Book ID
121321451
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
507 KB
Volume
30
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

Theoretical studies on the alkaline hydr
Theoretical studies on the alkaline hydrolysis of N-Methylcarbamates
โœ Toshiyuki Katagi ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 542 KB

The reaction mechanisms of the alkaline hydrolysis of N-methylcarbamates were studied using the AM1 method by assuming two possible pathways: (1) nucleophilic attack of hydroxide ion on the car-bony1 carbon to give a tetrahedral complex followed by its breakdown to carbamic acid (BA,~); and (2) prot