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The mechanism of substitution reactions of pentamminecobalt(III) complexes. Product distributions in the induced aquation of some [Co(NH3)5X]2+ ions in the presence of added anions

✍ Scribed by Buckingham, David A.; Olsen, I. I.; Sargeson, Alan M.; Satrapa, H.


Book ID
125994819
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
706 KB
Volume
6
Category
Article
ISSN
0020-1669

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The Kinetics of Substitution Reactions o
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In aqueous solution, bis(nucleoside) complexes formed by the reaction of cis-[Pt(NH3)2(H2O)2]2+ with an excess of either adenosine (ado) or a mixture of adenosine and guanosine (guo) undergo a slow N7--> N1 linkage isomerisation in the adenine moiety. The isomerisation probably involves the breaking