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The mechanism of substitution of (π-olefin)iron tetracarbonyl complexes by triphenylphosphine: Solvent effects

✍ Scribed by G. Cardaci

Book ID
108347202
Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
616 KB
Volume
76
Category
Article
ISSN
0022-328X

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✍ G. Cardaci 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 483 KB 👁 1 views

## Abstract The kinetics of the reaction have been studied in toluene solution. The reaction occurs by a dissociative mechanism and the observation of an appreciable mass law retardation effect shows that Fe(CO)~4~ is produced as an intermediate. Analysis of the effect of the substituent X on t