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The Mechanism of Stereoselection in Rh-Catalyzed Asymmetric Hydrogenation: A General Approach for Predicting the Sense of Enantioselectivity

✍ Scribed by Ilya D. Gridnev; Tsuneo Imamoto


Publisher
John Wiley and Sons
Year
2004
Weight
7 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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Modular P-Chirogenic Aminophosphane-Phos
✍ Christophe Darcel; Dominique Moulin; Jean-Christophe Henry; Michaël Lagrelette; 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 258 KB

## Abstract An original series of P‐chirogenic aminophosphane‐phosphinite (AMPP) ligands has been synthesized from (+)‐ or(–)‐ephedrine in 23 to 61 % overall yields by a versatile three‐step methodology. The AMPP ligands, bearing either one or two P‐chirogenic centers, were used in the form of rhod