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The mechanism of poly-NEDD8 chain formation in vitro

✍ Scribed by Yu Ohki; Norikazu Funatsu; Natsumi Konishi; Tomoki Chiba


Book ID
116298275
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
453 KB
Volume
381
Category
Article
ISSN
0006-291X

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Polyethylene produced by a vanadium-based polymerization catalyst contains long-chain branching as determined by NMR and rheology, even though the polymer has very low levels of vinyl unsaturation. A new mechanism is proposed for the formation of the long-chain branching, which involves COH bond act