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The mechanism of olefin formation from benzylic sulfoxides using phenyllithium

✍ Scribed by R.H. Schlessinger; G.S. Ponticello; A.G. Schultz; I.S. Ponticello; J.M. Hoffman

Publisher: Elsevier Science
Year: 1968
Tongue: French
Weight: 179 KB
Volume: 9
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)72377-x

No coin nor oath required. For personal study only.

✦ Synopsis

Benzylsulfoxide (I)' has been reported to react with potassium t-butoxide in

dimethyl sulfoxide or dimethylformamide to give stilbene in moderate yield.2 The mechanism proposed for this reaction is given as follows:

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