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The Mechanism of Hydrolysis of Schiff Bases Derived from Aliphatic Amines

✍ Scribed by Cordes, E. H.; Jencks, W. P.

Book ID
119953723
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
798 KB
Volume
85
Category
Article
ISSN
0002-7863

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Aza Cope rearrangement of schiff bases d
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✍ Thomas L. Gilchrist; AntΓ³nio M.d'A.Rocha Gonsalves; Teresa M.V.D. Pinbo e Melo πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 French βš– 151 KB

Methyl l-(benzylideneamino)acryiaIe 1 acls as a dienophile in its reaction with cyclopentadiene and gives the oorbomene eskr 2a. This undergoes an aza Cope rearrangemew at nxnn temperature to give the tehahydropyridine 3a. An analogous rearrangement of the imine 5 ties place.