## Altatraet4omparative studies of the mechanism of anodic oxidation of N-phenyl-pphenylenediamine (NPPD) on a bare platinum 'electrode as well as on platinum coated with poly-3-methylthiophene (P3MT) or polythiophene (PT) films have been carried out. The shift of the voltammetric peak potential c
The mechanism of heterogeneous electron transfer
β Scribed by X. de Hemptinne
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 427 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0037-9646
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Using molecular dynamics computer simulation technique we studied the effect of the ion-electrode contact on the energetics of electron transfer reactions. We observed that when the solvation shell of the ion undergoes large changes due to the ion transfer from the bulk to the interface, the energet
Some recent studies of inner-sphere and outer-sphere electron-transfer reactions in solution are described. Various indirect criteria for determining the mechanisms of electron-transfer re actions and the question of ligand bridging at electrodes are discussed.
## Abstrae~lvent effects studied in simple heterogeneous redox reactions, and for amalgam formation reactions have been reviewed. It is emphasized that on the basis of a regression analysis of the data, solvent effects relating to the pm-exponential factor of the electron transfer rate wnstant can