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The Mechanism of Halogen-atom Catalyzed cis—trans Isomerization. Studies with Bromine and Dibromoethylene

✍ Scribed by Steinmetz, Hyman; Noyes, Richard M.


Book ID
126896777
Publisher
American Chemical Society
Year
1952
Tongue
English
Weight
863 KB
Volume
74
Category
Article
ISSN
0002-7863

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CNDO/2 study of the mechanism and kineti
✍ Z. Slanina 📂 Article 📅 1977 🏛 Elsevier Science 🌐 English ⚖ 433 KB

Complete optimization of the molecular geometry of NzF2 confirmed the two previously assumed activated complexes (AC's) for the title reaction. The contributions of both AC's were precisely weighed up in terms of the activated-complex theory. The possibdity of an autocatalysed chain mechanism is dis