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The mechanism of diffusion in anomalous b.c.c. transition metals

✍ Scribed by G.B. Gibbs

Publisher: Elsevier Science
Year: 1964
Weight: 253 KB
Volume: 12
Category: Article
ISSN: 0001-6160
DOI: 10.1016/0001-6160(64)90117-8

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Eow Zener's analysis and any self-consistent elastic Bat. 15, 144 (1967). model of saddle-point deformation has not the internal 2. J. E. WORS~M, M. K. %RLKII?SON and c. G. kb%Z% J.

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Now wvaph = -Pwv2h so that (aAG/ap)T = AV and any pressure-variation of AF (through elastic moduli) is irrelevant. A lattice diffusivity increasing with increasing pressure implies a negative activation volume AV. However, it is not certain that the simple effect on lattice diffusion was measured

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