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The mechanism of densification during sintering of metallic particles

✍ Scribed by G.C Kuczynski


Publisher
Elsevier Science
Year
1956
Weight
542 KB
Volume
4
Category
Article
ISSN
0001-6160

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✦ Synopsis


The possible mechanisms which may bring about shrimkage of pores dnring sintering are discussed. In view of the Alexander-Balufll experiment, only twa such mechanisms are possible: (1) diffusion along grain boundaries, (2) volume diffusion with sinks at grain boundaries (Nabarro-Herring microcreep). The excess vacancies are transmitted to the grain boundaries and through their network out of the compact. The probability of occurrence of these mechanisms is discussed. It is concluded that the volume-diffusion mechanism is the more probable one. M~CANrS~ DE L'AUGME~AT~~N DE DENSITE LGRS DW FRI~AGE DES PARTICWLES MKTALLIQUES Les mecanismes possiblea qui peuvent faire disparaitre les pores pendant le frittage sont discutes. D'apres les experiences d'Alexander et Baluffi, deux m&nismes seulement sont possibles: 1 "-Diffusion le long des joints de grain. 2"-Diffusion en volume aveo disparition des lacunes sur lea joints de grain (mecaniame de Nabarro et Herring). Les lacunes cn exclrs diffusent vers les joints de grain et, par leur &eau, hors du cornprim& La probabilite de ces divers m&canismes eat discut&e et ii est oonclu que la diffusion en volumes est b m&car&me le plus probable. UBER DEN MECHANISMUS DER VERDICHTUNG BEIM SINTERN VON METALLISCHEN TEILCHEN Die mijglichen Mechanismen, die eine Sohrumpfung van Poren wahrend des Sinterns verursachen k&men, werden diskutiert. Nach dem Alexander-Baluffi Experiment sind nur zwei sobhe Mechanismen miiglich; (1) die DifYusion entlang der Korngrenzen und (2) die Volumendi~usion mit L&hem an den Korngrenzen (Nabarro-Herring Mi~okr~echen). Die iiberschtissigen Leer&&en warden zu den Korngrenzen und durch deren Netzwerk aus dem Sin&k&per hinaus befiirdert. Die Moglichkeit des Au&r&ens dieser Mechanismen wird diakutiert. Es wird der Schluss gezogen, dass die Volumendiffusion der wahrscheinlichere Vorgang ist.


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