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The Mechanism of CX (X=F, Cl, Br, and I) Bond Activation in CX4 by a Stabilized Dialkylsilylene

✍ Scribed by Chi-Hui Chen; Ming-Der Su


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
596 KB
Volume
13
Category
Article
ISSN
0947-6539

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## Abstract Quantum chemical calculations have been performed to study the complex of MCN‐LiCN‐XCCH (M = H, Li, and Na; X = Cl, Br, and I). The aim is to study the cooperative effect between halogen bond and lithium bond. The alkali metal has an enhancing effect on the lithium bond, making it incre