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The mechanism of cleavage of C-H bonds by coenzyme B12: The role of ‘carbenoid’ metal-alkyl species in catalysis

✍ Scribed by Valla Amir-Ebrahimi; Robert Hamilton; Manohar V. Kulkarni; Edward A. McIlgorm; Thomas R.B. Mitchell; John J. Rooney

Publisher
Elsevier Science
Year
1983
Weight
438 KB
Volume
22
Category
Article
ISSN
0304-5102

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Molecular mechanics force field constants have been derived correlated with their calculated cone angles. The force field has been used to analyse some conformational features of for alkylcobaloximes, (alkyl)Co(DH) 2 L (DH = monoanion of dimethylglyoxime and L = planar N-donor ligand), these compoun