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The mechanism of chain branching in the oxidation of ethoxyquin

✍ Scribed by T. D. Nekipelova; A. B. Gagarina; N. M. Émanuél'

Book ID
112438456
Publisher
Springer
Year
1979
Tongue
English
Weight
377 KB
Volume
28
Category
Article
ISSN
1573-9171

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Polyethylene produced by a vanadium-based polymerization catalyst contains long-chain branching as determined by NMR and rheology, even though the polymer has very low levels of vinyl unsaturation. A new mechanism is proposed for the formation of the long-chain branching, which involves COH bond act